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The influence of fuel volatility on the thermal efficiency of premixed diesel combustion was evaluated with three ordinary diesel fuels with different distillation temperature distributions and also with a primary reference fuel with an octane number of 20 (PRF20) as a high volatility fuel. The experiments were conducted on a single-cylinder DI diesel engine for the premixed diesel combustion with a single injection at 11% intake oxygen concentration and conventional diesel combustion with a pilot fuel injection at 21% intake oxygen concentration. With the premixed diesel combustion, the indicated thermal efficiencies with the ordinary diesel fuels were lower than with PRF20 although the shapes of the rate of heat release and the combustion efficiencies calculated from the exhaust gas components were almost unchanged. With the conventional diesel combustion, the indicated thermal efficiencies with the ordinary diesel fuels and PRF20 were similar.

The effects of blending ETBE to diesel fuel on the characteristics of low temperature diesel combustion and exhaust emissions were investigated in a naturally-aspirated DI diesel engine with large rates of cooled EGR. Low temperature smokeless diesel combustion in a wide EGR range was established with ETBE blended diesel fuel as mixture homogeneity is promoted with increased premixed duration due to decreases in ignitability as well as with improvement in fuel vaporization due to the lower boiling point of ETBE. Increasing the ETBE content in the fuel helps to suppress smoke emissions and maintain efficient smokeless operation when increasing EGR, however a too high ETBE content causes misfiring at larger rates of EGR. While the NOx emissions increase with increases in ETBE content at high intake oxygen concentrations, NOx almost completely disappears when reducing the intake oxygen content below 14 % with cooled EGR.

The effect of after-injection on exhaust gas emissions from a DI diesel engine with a common rail injection system was experimentally investigated for a range of operating conditions. The results showed that over the whole of the operating range, some reduction in smoke emissions can be achieved with after-injection, without deterioration in thermal efficiency and other emission characteristics. The optimum quantity of after-injection for smoke reduction is 20% of the total fuel supply, and the optimum timing is just after the main injection. Visualization in a bottom view type engine showed that with after-injection, soot formation in the main-injection decrease more due to a smaller quantity of fuel than without after-injection, and soot formation with after-injection is insignificant.

The effect of eight kinds of oxygenated agents added to diesel fuels on the combustion and emissions was investigated in a DI diesel engine. The results showed significant smoke and particulate suppression without increases in NOx with every oxygenated agent. The emissions decreased linearly with increasing oxygen content in the fuels, almost regardless of the kind of oxygenated agent. The improvement in smoke and particulate emissions with the oxygenated agent addition was more significant for lower volatility fuels. Combustion analysis with the two-dimensional two color method showed that soot concentration in the flame during the combustion process decreased with the addition of the oxygenated agent while the flame temperature distribution was almost unchanged.

Dual fuel combustion with premixed natural gas as the main fuel and diesel fuel as the ignition source was investigated in a 0.83 L, single cylinder, DI diesel engine. At low loads, increasing the equivalence ratio of natural gas to around 0.5 with intake throttling makes it possible to reduce the THC and CO emissions as well as to improve the thermal efficiency. At high loads, increasing the boost pressure moderates the combustion, but increases the THC and CO emissions, resulting in deterioration of the thermal efficiency. The EGR is essential to suppress the rapid combustion. As misfiring occurs with a compression ratio of 14.5 and there is excessively rapid combustion with 18.5 compression ratio, 16.5 is a suitable compression ratio.

Port injection of ethanol addition as an ignition inhibitor was implemented to control ignition timing and expand the operating range in DME fueled HCCI combustion. The ethanol reduced the rate of low-temperature oxidation and consequently delayed the onset of the high-temperature reaction with ultra-low NOx over a wide operating range. Along with the ethanol addition, changes in intake temperature, overall equivalence ratio, and engine speed are investigated and shown to be effective in HCCI combustion control and to enable an extension of operation range. A chemical reaction analysis was performed to elucidate details of the ignition inhibition on low-temperature oxidation of DME-HCCI combustion.

Diesel particulate filters (DPF) are widely used in diesel engines, and forced regeneration is necessary to remove particulate matter (PM) accumulating on the DPF. This may be achieved with fuel injected after the main combustion is complete, the socalled “post fuel injection”, and supplied to the diesel oxidation catalyst (DOC) upstream of the DPF. This increases the exhaust gas temperature in the DOC and the DPF is regenerated with the high temperature gas flow. In most cases, the post fuel injection takes place at 30-90CA ATDC, and fuel may impinge on and adhere to the cylinder liner wall in some cases. Buddie and Pischinger [1] have reported a lubricant oil dilution with the post fuel injection by engine tests and simulations, and adhering fuel is a cause of worsening fuel consumption. In this paper, the impingement and adhesion of post diesel fuel injections on the cylinder liner was investigated by an optical method with a high pressure constant volume chamber (ϕ110mm, 883cm3).

The HCCI engine offers the potential of low NOx emissions combined with diesel engine like high efficiency, however HCCI operation is restricted to low engine speeds and torques constrained by narrow noise (HCCI knocking) and misfiring limits. Gasoline like fuel vaporizes and mixes with air, but the mixture may auto-ignite at the same time, leading to heavy HCCI knocking. Retarding the CA50 (the crank angle of the 50% burn) is well known as a method to slow the maximum pressure rise rate and reduce HCCI knocking. The CA50 can be controlled by the fuel composition, for example, di-methyl ether (DME), which is easily synthesized from natural gas, has strong low temperature heat release (LTHR) characteristics and ethanol generates strong LTHR inhibitor effects. The utilization of DME-ethanol binary blended fuels has the potential to broaden the HCCI engine load-speed range.

Forced ignition with glow plugs has great potential for the utilization of alcohol fuels in diesel engines. However, the installation of glow plugs may cause misfiring or knocking in parts of the operating range. This paper presents an analysis of the factors influencing the ignition characteristics of ethanol in a glow plug-assisted diesel engine; these factors may be classified into two categories: the factors related to the temperature history of the drop lets before contact with the glow plug, and those related to the probability of contact. By optimizing these factors, the combustion difficulties were successfully eliminated over the whole operating range, and engine performance comparable with conventional diesel operation was achieved.

Characteristics of diesel combustion with low cetane number fuels with similar distillation temperatures to ordinary diesel fuel, including fuels with cetane number 32 and 39 (LC32, LC39), and a blend of n-cetane (n-hexadecane) and iso-cetane (2, 2, 4, 4, 6, 8, 8-heptamethylnonane) with cetane number 32 (CN32), were investigated. The effects of cooled exhaust gas recirculation (EGR) and pilot injection on characteristics of combustion and exhaust gas emissions with these fuels were examined in a naturally aspirated, single cylinder, diesel engine equipped with a common-rail fuel injection system. Even with the low cetane number fuels, quiet combustion with low levels of exhaust gas emissions comparable to ordinary diesel fuel was established by suitable control of intake oxygen levels and pilot injections.

Unregulated emissions from a DI diesel engine with ultra-high EGR low temperature combustion were analyzed using Fourier transform infrared (FTIR) spectroscopy and the reduction characteristics of both regulated and unregulated emissions by two exhaust catalysts were investigated. With ultra-high EGR suppressing the in-cylinder soot and Nox formation as well as with the exhaust catalysts removing the engine-out THC and CO emissions, clean diesel operation in terms of ultra-low regulated emissions (Nox, PM, THC, and CO) is established in an operating range up to 50% load. To realize smokeless low temperature combustion at higher loads, EGR has to be increased to a rate with the overall (average) excess air ratio less than the stoichiometric ratio.

Dual fuel combustion with premixed ethanol as the main fuel and direct injection of diesel fuel as an ignition source poses problems including large unburned emissions and excessively rapid combustion. In this report the influence of compression ratios, injection timings of diesel fuel, and intake oxygen concentrations was systematically investigated in a modern diesel engine. The combustion process was classified into three stages: the first rapid combustion of diesel fuel and the ethanol mixture entrained into the diesel fuel spray; the second mild combustion with flame propagation of the ethanol mixture; and the third rapid combustion with auto-ignition of the unburned ethanol mixture without knocking. The third stage combustion occurs occasionally at several operating conditions and has been termed as PREMIER (premixed mixture ignition in the end-gas region) combustion.

The influence of aromatic content in fuels on the soot and NOx emissions from a diesel engine was analyzed under controlled ignition lags with spark-assisted operation. Monocyclic aromatic hydrocarbons and n-hexane mixtures were used as fuels, and the aromatic content was varied from 0 to 75 v-%. The experiments showed that, at the same equivalence ratio and regardless of the molecular structure of the fuel, the soot concentration in the exhaust gas could be described by a linear-combination function with two variables representing the ignition lag and C/H atom-ratio of the fuels. For unchanged ignition lags, the soot emissions increased linearly with increased C/H atom-ratios, which are controlled by the aromatic content. The degree of increase in soot emissions with increasing C/H atom-ratio decreased with decreasing equivalence ratios. The NOx emission increased slightly with increases in the C/H atom-ratio and ignition lag.

To reduce NOx emissions from diesel engines, the urea-SCR (selective catalytic reduction) system has been introduced commercially. In urea-SCR, the freezing point of the urea aqueous solution, the deoxidizer, is −11°C, and the handling of the deoxidizer under cold weather conditions is a problem. Further, the ammonia escape from the catalyst and the generation of N2O emissions are also problems. To overcome these disadvantages of the urea-SCR system, the addition of a hydrocarbon deoxidizer has attracted attention. In this paper, a micro-reactor SCR system was developed and attached to the exhaust pipe of a single cylinder diesel engine. With the micro-reactor, the catalyst temperature, quantity of deoxidizer, and the space velocity can be controlled, and it is possible to use it with gas and liquid phase deoxidizers. The catalyst used in the tests reported here is Ag(1wt%)-γAl2O3.

The effects of several fuel property variables on the emissions from a D.I. diesel engine were individually analyzed. The results showed that the smoke and dry soot increased with increased kinematic viscosity, shorter ignition lag, and higher aromatic content, especially at high equivalence ratios. Over the whole range of equivalence ratios, SOF depended on and increased with only ignition lag. The NOx improved slightly with increased kinematic viscosity, higher ignitability, and decreased aromatic content. The unburnt HC also improved with decreased kinematic viscosity and higher ignitability. The distribution shape of distillation curves had little influence on the emissions.

The dependence of ultra-high EGR low temperature diesel combustion on fuel properties including cetane number and distillation temperature was investigated with a single-cylinder, naturally aspirated, 1.0 L, common rail DI diesel engine. Decreasing cetane number in fuels significantly reduces smoke emission due to an extension in ignition delay and the subsequent improvement in mixture formation. Smokeless combustion, ultra-low NOx, and efficient operating range with regard to EGR and IMEP are significantly extended by decreasing fuel cetane number. Changes in fuel distillation temperature do not result in significant differences in smoke emission and thermal efficiency for ultra-high EGR operation, and smokeless operation is established even with higher distillation temperature fuels as long as fuel cetane number is sufficiently low.

The combustion characteristics in a partially premixed charge compression ignition (PCCI) engine with n-hexane were compared with ordinary diesel fuel to evaluate combustion improvements with lower distillation-temperature fuels. In the PCCI engine, a lean mixture was formed reasonably with early stage injection and the additional fuel was supplied with a second stage fuel injection after ignition. With n-hexane, thermal efficiency improved while simultaneously maintaining low NOx and smokeless combustion. A CFD analysis simulated the mixture formation processes and showed that the uniformity of the mixture with the first stage injection improves with lower distillation-temperature fuels.

Combustion and exhaust gas emissions of alcohol and vegetable oil blends including a 20% ethanol + 40% 1-butanol + 40% vegetable oil blend and a 50% 1-butanol + 50% vegetable oil blend were examined in a single cylinder, four-stroke cycle, 0.83L direct injection diesel engine, with a supercharger and a common rail fuel injection system. A 50% diesel oil + 50% vegetable oil blend and regular unblended diesel fuel were used as reference fuels. The boost pressure was kept constant at 160 kPa (absolute pressure), and the cooled low pressure loop EGR was realized by mixing with a part of the exhaust gas. Pilot injection is effective to suppress rapid combustion due to the lower ignitability of the alcohol and vegetable oil blends. The effects of reductions in the intake oxygen concentration with cooled EGR and changes in the fuel injection pressure were investigated for the blended fuels.

Light naphtha, which exhibits two-stage ignition, was induced from the intake manifold for ignition enhancement and a low ignitability fuel or water, which does not exhibit low temperature oxidation, was directly injected early in the compression stroke for ignition suppression in an HCCI engine. Their quantitative balance was flexibly controlled to optimize ignition timing according to operating condition. Ultra-low NOx and smokeless combustion without knocking or misfiring was realized over a wide operating range. Alcohols inhibit low temperature oxidation more strongly than other oxygenated or unoxygenated hydrocarbons, water, and hydrogen. Chemical kinetic modeling for methanol showed a reduction of OH radical concentration before the onset of low temperature oxidation, and this may be the main mechanism by which alcohols inhibit low temperature oxidation.

Direct injection of various ignition suppressors, including water, methanol, ethanol, 1-propanol, hydrogen, and methane, was implemented to control ignition timing and expand the operating range in an HCCI engine with induced DME as the main fuel. Ultra-low NOx and smoke-less combustion was realized over a wide operating range. The reaction suppressors reduced the rate of low-temperature oxidation and consequently delayed the onset of high-temperature oxidation. Analysis of the chemical kinetics showed a reduction of OH radical in the premixed charge with the suppressors. Among the ignition suppressors, alcohols had a greater impact on OH radical reduction resulting in stronger ignition suppression. Although water injection caused a greater lowering of the temperature, which also suppressed ignition, the strong chemical effect of radical reduction with methanol injection resulted in the larger impact on suppression of oxidation reaction rates.